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ORGLIST: Stability of Ar-N2-Zn-Br3/Ar-Zn-I3

From: "krishna.maringanti" <krishna.maringanti>
Subject: ORGLIST: Stability of Ar-N2-Zn-Br3/Ar-Zn-I3
Date: Sun, 8 Sep 2013 20:27:58 -0700 (PDT)
A couple of publications from mid 1980s discussed about bromo-de-amination of racemic and chiral 1,1'-binaphthyl-2,2'-diamine via the formation of Ar-N=N-Zn-Br3 species (presumed formation- no direct evidence on the emperical formula). The question is, did any one come across the intermediate? Any idea on the stability and its compatibility with water? Thank you for the help in advance.

Krishna M

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Krishna M, PhD., 
MSD Consultancy
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